Why’d you inject his stifles?
I had a gelding who started doing that out of the blue (and had a super good, reasonable, calm brain), and the answer was locking stifles. His stifle would lock and it would totally freak him out and he would bolt. Totally different reaction, however, than a “naughty bolt.” It was short-lived…5 or 6 strides at most and then back to normal.
Finally figured it out one day watching a video of him jumping where he knocked down a crossrail (totally unlike him), and you could see the stifle lock before the fence, he landed and let loose a massive buck and then cantered away. My vet said, “yep, sometimes the only way for a horse to unlock a stifle is to buck.” That was the only time I ever noticed it happening over a jump (and the only time he reacted with a buck), but it was clear as day on video. Normally it was while we were cantering and he would “scoot” away as though a bee had just stung him or something. Had my vet and bodyworker fix his pelvis and the behavior disappeared.
So my vote is something “pinching” or hurting or getting stuck. I might start by looking at stifles and then go from there.