What’s the link for your info?
This is where I got mine:
https://www.southernstates.com/docs/eq/0610_horsefeedvalues.pdf
It says the NSC is 29%, with the starch + ESC being the 21.9% from your list. Arguably, the accepted definition of NSC is starch + WSC. It’s those water-soluble sugars which leach out when you soak hay to reduce the NSC.